Methods
References: USEPA Methods for Analysis of Water and Wastes, Method 410.4 (1983). APHA Standard Methods, 21st ed., Method 5220 D (2005). A. M. Jirka and M. J. Carter, "Micro Semi-Automated Analysis of Surface and Wastewaters for Chemical Oxygen Demand," Analytical Chemistry, Vol. 47, p.1397 (1975). J. A. Winter, "Method Research Study 3, Demand Analysis, An Evaluation of Analytical Methods for Water and Wastewater," USEPA, 1971. ASTM D 1252-06, Chemical Oxygen Demand (Dichromate Oxygen Demand) of Water, Test Method B.
The determination of Chemical Oxygen Demand (COD) is widely used in municipal and industrial laboratories to measure the overall level of organic contamination in wastewater. The contamination level is determined by measuring the equivalent amount of oxygen required to oxidize organic matter in the sample.
CHEMetrics offers two dichromate reactor digestion methods for fast, easy, safe determinations of ultra-low, low-, mid-, and high-range COD levels in wastewater: the USEPA-approved Method*, and a mercury-free method. The products using the USEPA-approved method contain mercuric sulfate in the reagent to eliminate chloride interferences. The mercury-free product line is applicable when chloride interference is not a concern and USEPA reporting is not required.