Copper-tin-(zinc) electrolytes as
nickel-free alternatives
Since 1981, MIRALLOY* has been a good alternative for the
nickel free coating of costume jewellery. Particularly endange-
red skin zones are the earlobes because of ear-piercing, neck
and arms (costume jewellery and wrist watches).
MIRALLOY” is an alkaline-cyanide electrolyte for depositing
copper-tin or copper-tin-zinc coatings in both barrel and rack
operation. Depending on the type of electrolyte used, either
white or yellow layers can be deposited. White coatings contain
about 55 % copper, 30 % tin and 15 % zinc. Yellow coatings
have average alloy percentages of 80 % copper, 17.5 % tin and
2.5% zinc; 80 % copper and 20 % tin, or 85 % copper, 10 % tin
and 5 % zinc.
MIRALLOY" coatings are characterized by a very good metal dis-
tribution and, depending on the type of electrolyte used, high
tarnish resistance, levelling, abrasion resistance and excellent
corrosion resistance.
Subsequent plating with gold, rhodium or other precious metals
is unproblematic if suitable processes and pre-tieatment steps
are chosen, this will provide optimum corrosion protection.