Total nitrogen (TN) refers to the nitrogen content in soluble and suspended particles in water, including nitrite nitrogen, nitrate nitrogen, inorganic ammonium salt, dissolved ammonia and nitrogen in most organic nitrogen-containing compounds. Lakes and reservoirs contain excessive nitrogen and phosphorus substances, resulting in vigorous reproduction of phytoplankton and eutrophication. Therefore, total nitrogen has also become an important index to control water quality.
Working principle
In aqueous solution above 60 ℃, potassium persulfate can decompose to produce potassium bisulfate and atomic oxygen, and potassium bisulfate dissociates in solution to produce hydrogen ions, so the decomposition process can be promoted to be complete in alkaline medium of sodium hydroxide. At 120 ~ 124 ℃, the decomposed atomic oxygen can transform the nitrogen of nitrogen-containing compounds into nitrate in water samples, and the organic matter is oxidized and decomposed at the same time in this process. The absorbance A220 and A275 can be measured by ultraviolet spectrophotometry at wavelengths of 220nm and 275nm respectively, and the corrected absorbance A can be calculated according to the formula A=A220-2A275.