The common laminating materials PP, PE film is a non-polar polymer material, stable chemical performance, small surface tension, difficult to adhere to ink combined influenced by opening agents, antistatic agents, aging agents, etc. added during synthetic resin composition. In the packaging PE membrance and paper composite gap injected into a certain concentration of ozonation gas, which can oxidize the surface of the laminating materials rough instantly so as to increase the adhesion of the membrance effectively by use of the strong oxidation of the ozone. The composite efficiency is high and pollution-free, green environmental protection.